It has much more liquid, protein and fat. It changes the whole consistency of the cake.
However, there is such a thing as a peanut butter cake (link in source) and you could probably replace the peanut butter with nutella and halve the sugar and come out with something pretty good.
But what I'd do is just make a regular yellow butter or chiffon cake and frost it with straight up nutella. That would be really tasty.
Edit: Ooh, there is a nutella cake! Go here: http://www.bigcitylittlekitchen.com/2007鈥?/a>
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